This belief in long ages for the earth and the existence of life is derived largely from radiometric dating. These long time periods are computed by measuring the ratio of daughter to parent substance in a rock and inferring an age based on this ratio.
This age is computed under the assumption that the parent substance say, uranium gradually decays to the daughter substance say, lead , so the higher the ratio of lead to uranium, the older the rock must be. Of course, there are many problems with such dating methods, such as parent or daughter substances entering or leaving the rock, as well as daughter product being present at the beginning. Here I want to concentrate on another source of error, namely, processes that take place within magma chambers.
To me it has been a real eye opener to see all the processes that are taking place and their potential influence on radiometric dating. Radiometric dating is largely done on rock that has formed from solidified lava. Lava properly called magma before it erupts fills large underground chambers called magma chambers. Most people are not aware of the many processes that take place in lava before it erupts and as it solidifies, processes that can have a tremendous influence on daughter to parent ratios.
Such processes can cause the daughter product to be enriched relative to the parent, which would make the rock look older, or cause the parent to be enriched relative to the daughter, which would make the rock look younger. This calls the whole radiometric dating scheme into serious question. Geologists assert that older dates are found deeper down in the geologic column, which they take as evidence that radiometric dating is giving true ages, since it is apparent that rocks that are deeper must be older.
But even if it is true that older radiometric dates are found lower down in the geologic column, which is open to question, this can potentially be explained by processes occurring in magma chambers which cause the lava erupting earlier to appear older than the lava erupting later. Lava erupting earlier would come from the top of the magma chamber, and lava erupting later would come from lower down. A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.
Mechanisms that can alter daughter-to-parent ratios What happens when magma solidifies and melts and its implications for radiometric dating The following quote from The Earth: The general idea is that many different minerals are formed, which differ from one another in composition, even though they come from the same magma.
The mineral makeup of an igneous rock is ultimately determined by the chemical composition of the magma from which it crystallized. Such a large variety of igneous rocks exists that it is logical to assume an equally large variety of magmas must also exist. However, geologists have found that various eruptive stages of the same volcano often extrude lavas exhibiting somewhat different mineral compositions, particularly if an extensive period of time separated the eruptions.
Evidence of this type led them to look into the possibility that a single magma might produce rocks of varying mineral content. A pioneering investigation into the crystallization of magma was carried out by N.
Bowen in the first quarter of this century. Bowen discovered that as magma cools in the laboratory, certain minerals crystallize first. At successively lower temperature, other minerals begin to crystallize as shown in Figure 3. As the crystallization process continues, the composition of the melt liquid portion of a magma, excluding any solid material continually changes. For example, at the stage when about 50 percent of the magma has solidified, the melt will be greatly depleted in iron, magnesium, and calcium, because these elements are found in the earliest formed minerals.
But at the same time, it will be enriched in the elements contained in the later forming minerals, namely sodium and potassium. Further, the silicon content of the melt becomes enriched toward the latter stages of crystallization. Bowen also demonstrated that if a mineral remained in the melt after it had crystallized, it would react with the remaining melt and produce the next mineral in the sequence shown in Figure 3.
For this reason, this arrangement of minerals became known as Bowen's reaction series. On the upper left branch of this reaction series, olivine, the first mineral to form, Ml] react with the remaining melt to become pyroxene. This reaction will continue until the last mineral in the series, biotite mica, is formed. This left branch is called a discontinuous reaction series because each mineral has a different crystalline structure. Recall that olivine is composed of a single tetrahedra and that the other minerals in this sequence are composed of single chains, double chains, and sheet structures, respectively.
Ordinarily, these reactions are not complete so that various amounts of each of these minerals may exist at any given time. The right branch of the reaction series is a continuum in which the earliest formed calcium-rich feldspar crystals react with the sodium ions contained in the melt to become progressively more sodium rich. Oftentimes the rate of cooling occurs rapidly enough to prohibit the complete transformation of calcium-rich feldspar into sodium-rich feldspar.
In these instances, the feldspar crystals will have calcium-rich interiors surrounded by zones that are progressively richer in sodium.
During the last stage of crystallization, after most of the magma has solidified, the remaining melt will form the minerals quartz, muscovite mica, and potassium feldspar. Although these minerals crystallize in the order shown, this sequence is not a true reaction series. Bowen demonstrated that minerals crystallize from magma in a systematic fashion. But how does Bowen's reaction series account for the great diversity of igneous rocks?
It appears that at one or more stages in the crystallization process, a separation of the solid and liquid components of a magma frequently occurs. This can happen, for example, if the earlier formed minerals are heavier than the liquid portion and settle to the bottom of the magma chamber as shown in Figure 3. This settling is thought to occur frequently with the dark silicates, such as olivine. When the remaining melt crystallizes, either in place or in a new location if it migrates out of the chamber, it will form a rock with a chemical composition much different from the original magma Figure 3.
In many instances the melt which has migrated from the initial magma chamber will undergo further segregation. As crystallization progresses in the " new" magma, the solid particles may accumulate into rocklike masses surrounded by pockets of the still molten material. It is very likely that some of this melt will be squeezed from the mixture into the cracks which develop in the surrounding rock.
This process will generate an igneous rock of yet another composition. The process involving the segregation of minerals by differential crystallization an separation is called fractional crystallization.
At any stage in the crystallization process the melt might be separated from the solid portion of the magma. Consequently, fractional crystallization can produce igneous rocks having a wide range of compositions. Bowen successfully demonstrated that through fractional crystallization one magma can generate several different igneous rocks.
However, more recent work has indicated that this process cannot account for the relative quantities of the various rock types known to exist. Although more than one rock type can be generated from a single magma, apparently other mechanisms also exist to generate magmas of quite varied chemical compositions. We will examine some of these mechanisms at the end of the next chapter. Illustration of how the earliest formed minerals can be separated from a magma by settling.
The remaining melt could migrate to a number of different locations and, upon further crystallization, generate rocks having a composition much different from the parent magma. So we see that many varieties of minerals are produced from the same magma by the different processes of crystallization, and these different minerals may have very different compositions. It is possible that the ratio of daughter to parent substances for radiometric dating could differ in the different minerals.
Clearly, it is important to have a good understanding of these processes in order to evaluate the reliability of radiometric dating. Another quotation about fractionation follows: Faure discusses fractional crystallization relating to U and Th in his book p.
These values may be taken as an indication of the very low abundance of these elements in the mantle and crust of the Earth. In the course of partial melting and fractional crystallization of magma, U and Th are concentrated in the liquid phase and become incorporated into the more silica-rich products.
For that reason, igneous rocks of granitic composition are strongly enriched in U and Th compared to rocks of basaltic or ultramafic composition. Progressive geochemical differentiation of the upper mantle of the Earth has resulted in the concentration of U and Th into the rocks of the continental crust compared to those of the upper mantle. The concentration of Pb is usually so much higher than U, that a 2- to 3-fold increase of U doesn't change the percent composition much e.
We see that there are at least two kinds of magma, and U and Th get carried along in silica rich magma rather than in basaltic magma. This represents major fractionation. Of course, any process that tends to concentrate or deplete uranium or thorium relative to lead would have an influence on the radiometric ages computed by uranium-lead or thorium-lead dating. Also, the fact that there are two kids of magma could mean that the various radiometric ages are obtained by mixing of these kinds of magma in different proportions, and do not represent true ages at all.
Finally, we have a third quotation from Elaine G. Kennedy in Geoscience Reports, Spring , No. Contamination and fractionation issues are frankly acknowledged by the geologic community.
If this occurs, initial volcanic eruptions would have a preponderance of daughter products relative to the parent isotopes. Such a distribution would give the appearance of age.
As the magma chamber is depleted in daughter products, subsequent lava flows and ash beds would have younger dates. Such a scenario does not answer all of the questions or solve all of the problems that radiometric dating poses for those who believe the Genesis account of Creation and the Flood.
It does suggest at least one aspect of the problem that could be researched more thoroughly. Principles of Isotope Geology: John Wiley and Sons, Inc. It is interesting that contamination and fractionation issues are frankly acknowledged by the geologic community. But they may not be so familiar to the readers of talk.
So we have two kinds of processes taking place. There are those processes taking place when lava solidifies and various minerals crystallize out at different times. There are also processes taking place within a magma chamber that can cause differences in the composition of the magma from the top to the bottom of the chamber, since one might expect the temperature at the top to be cooler. Both kinds of processes can influence radiometric dates.
In addition, the magma chamber would be expected to be cooler all around its borders, both at the top and the bottom as well as in the horizontal extremities, and these effects must also be taken into account. For example, heavier substances will tend to sink to the bottom of a magma chamber. Also, substances with a higher melting point will tend to crystallize out at the top of a magma chamber and fall, since it will be cooler at the top. These substances will then fall to the lower portion of the magma chamber, where it is hotter, and remelt.
This will make the composition of the magma different at the top and bottom of the chamber. This could influence radiometric dates. This mechanism was suggested by Jon Covey and others. The solubility of various substances in the magma also could be a function of temperature, and have an influence on the composition of the magma at the top and bottom of the magma chamber. Finally, minerals that crystallize at the top of the chamber and fall may tend to incorporate other substances, and so these other substances will also tend to have a change in concentration from the top to the bottom of the magma chamber.